NO^+W^1△電子状態に収束する812Åリドベリー吸収帯の解析

フォーマット:

論文

責任表示:

竹澤, 賛三

言語:

英語

出版情報:

群馬大学医療技術短期大学部, 1985-03-30

著者名:

竹澤, 賛三  

掲載情報:

群馬大学医療技術短期大学部紀要

ISSN:

0389-7540    

巻:

5

開始ページ:

101

終了ページ:

110

バージョン:

VoR

概要:

application/pdf<br />Departmental Bulletin Paper<br />The rotational structure of the 812 Å absorption band, of which the upper state was assigned to be the v'=3 level of the Rydberg band converging to the W^1△ state of NO^ … +, is analyzed and its internuclear distance of the upper state is determined to be 1.33 Å from the rotational constant B=1.27cm^<-1>. The value is found to be supportive of the previous assumption that the band belongs to the first member of the Rydberg series mentioned above, because the internuclear distance of the W^1△ state is theoretically determined to be 1.34 Å. Since most of the bands observed in the region below 1000 Å are extremely diffuse because of autoionization. Any rotationally well-resolved band has not been observed except the author's previos work by means of the high resolution spectroscopy with the reciprocal dispersion of 0.6cm^<-1>/mm. 続きを見る